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Trends in Organic Chemistry   Volumes    Volume 1 
Abstract
Catalytic asymmetric synthesis using polymer-support
Shinichi Itsuno, Koichi Ito
Pages: 199 - 211
Number of pages: 13
Trends in Organic Chemistry
Volume 1 

Copyright © 1990 Research Trends. All rights reserved

ABSTRACT
 
Catalytic asymmetric syntheses Involving reduction of ketones and oximes, alkylation of aldehydes, and epoxidation of α,β-unsaturated ketones by the use of polymer-supported catalyst have been described. High enantioselectivities (>90% ee) were obtained in each case. The Insoluble polymeric catalysts can be recycled many times without significant loss of activity and used for a preparation of continuous-flow system.
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