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Current Topics in Analytical Chemistry   Volumes    Volume 12 
Abstract
Exploring the liquid and gas chromatographic data fusion for fat-spread food product classification according to their geographical origin
Ana M. Jiménez-Carvelo, Sanae Bikrani, M. Gracia Bagur-González, Mounir Nechar, Badredine Souhail, Luis Cuadros-Rodríguez
Pages: 61 - 72
Number of pages: 12
Current Topics in Analytical Chemistry
Volume 12 

Copyright © 2020 Research Trends. All rights reserved

ABSTRACT
 
Fat-spread products, including margarines, are an emulsion of water derived from vegetable and/or animal fats, which is obtained through a hydrogenation process. In the market there are different types of fat-spreads and their composition depends on the country where they are produced. It is therefore desirable to identify the geographic origin of each product. In this study, a multivariate analysis based on data fusion methodology (low- and mid- level) is carried out using partial least squares-discriminant analysis (PLS-DA) in order to classify fat-spread products according to their geographic origins (Spain, Morocco and France). The instrumental fingerprints acquired using reverse-high performance liquid chromatography coupled with a diode array detector ((RP)HPLC-DAD) and gas chromatography coupled with a mass spectrometry detector (GC-MS) were employed as analytical signals. The performance of the classifications was evaluated using proper classification metrics. Finally, low-level fusion turned out to achieve better results than mid-level fusion, obtaining sensitivity and precision values in external validation equal to 1.00.
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