The presented brief review reveals that the application of the method of Anodic Stripping Voltammetry is very useful for investigation of many aspects of electrodeposition of metals on semiconductors such as peculiarities of slow deposition at small and very small cathodic overpotentials, precise determination of the onset potential of this process, exploring of the energy states of electrodeposited metals, and so on (if anodic ionization of the deposited metal is possible). Detailed description of these applications is presented.