Home | My Profile | Contact Us
Research Trends Products  |   order gateway  |   author gateway  |   editor gateway  
ID:
Password:
Register | Forgot Password

Author Resources
 Author Gateway
 Article submission guidelines

Editor Resources
 Editor/Referee Gateway

Agents/Distributors
 Regional Subscription Agents/Distributors
 
Trends in Physical Chemistry   Volumes    Volume 2 
Abstract
Roles of potential energy and kinetic energy of electrons in conjugation and aromaticity
Hiroshi Ichikawa
Pages: 221 - 231
Number of pages: 11
Trends in Physical Chemistry
Volume 2 

Copyright © 1991 Research Trends. All rights reserved

ABSTRACT
 
Analysis of the potential- and kinetic-energy changes between conjugative and nonconjugative structures led to the conclusion that there were two different types of conjugations: The conjugative stability in vinylamine and aniline is produced by an excess decrease in the kinetic energy over the increase in the potential energy (kinetic-energy origin), while the conjugation of nitroethene or nitrobenzene causes an overwhelming decrease in the potential energy (potential-energy origin). The similar analysis was applied to understanding the intrinsic difference between topological aromaticity and so-called quasi-aromaticity. Topological aromatcs like benzene and naphthalene increase the kinetic energy by interrupting their conjugations more than the reference structures while quasi-aromatics as seen in polymethine-like molecules increase the potential energy by doing so. This indicates that extra stabilization in benzene or naphthalene is produced by lowering the kinetic energy of elections In marked contrast with this that in polymethine-like molecules is due to lowering the potential energy.
Buy this Article


 
search


E-Commerce
Buy this article
Buy this volume
Subscribe to this title
Shopping Cart

Quick Links
Login
Search Products
Browse in Alphabetical Order : Journals
Series/Books
Browse by Subject Classification : Journals
Series/Books

Miscellaneous
Ordering Information Ordering Information
Downloadable forms Downloadable Forms