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Current Topics in Electrochemistry   Volumes    Volume 22 
Abstract
Electrochemical synthesis of intermetallic and refractory compounds based on rare-earth metals in ionic melts: achievements and prospects
H. B. Kushkhov, M. R. Tlenkopachev
Pages: 57 - 77
Number of pages: 21
Current Topics in Electrochemistry
Volume 22 

Copyright © 2020 Research Trends. All rights reserved

ABSTRACT
 
This review is devoted to the electrochemical synthesis of intermetallic and refractory compounds based on rare-earth metals (REM), iron triad, boron and silicon in ionic melts. Data on the electrochemical behavior of lanthanides, iron, cobalt and nickel chloride complexes, as well as fluoroborate and fluorosilicate ions in chloride and chloride-fluoride melts are provided. Peculiarities of joint electroreduction processes between rare-earth metal ions and iron triad ions, fluoroborate and fluorosilicate ions are analyzed. The optimal parameters of the electrosynthesis of double and triple compounds based on rare-earth metals are discussed. Prospects for future development of high-temperature electrochemistry of rare-earth metals and technology solutions in the field of electrosynthesis of rare-earth metallic compounds in molten salts are discussed.
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