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Trends in Inorganic Chemistry   Volumes    Volume 4 
Abstract
Nanocomposites containing nanoclusters of metal phosphides of the nickel group elements: An overview
C. M. Lukehart, Stephen B. Milne, S. R. Stock, James E. Wittig
Pages: 9 - 12
Number of pages: 4
Trends in Inorganic Chemistry
Volume 4 

Copyright © 1996 Research Trends. All rights reserved

ABSTRACT
 
Molecularly doped silica xerogels are prepared by the addition of nickel, palladium, or platinum phosphine complexes containing bifunctional ligands to conventional silica sol-gel formulations. Subsequent thermal treatment under solely reducing conditions leads to decomposition of the precursor complex and to the formation of highly dispersed, crystalline nanoclusters of a single metal phosphide phase. Such dopant complexes act as single-source precursors for silica xerogel nanocomposites containing nanocluslers of Ni2P, Pd5P2, or PtP2. An overview of the synthesis and characterization of these nanocomposites is described.
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