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Current Trends in Medicinal Chemistry   Volumes    Volume 4 
Abstract
Further evidence that geometries of fungicides and pores in fungal wall must be compatible to show bioavailability
Herman Gershon, Muriel Gershon, Donald D. Clarke
Pages: 57 - 59
Number of pages: 3
Current Trends in Medicinal Chemistry
Volume 4 

Copyright © 2006 Research Trends. All rights reserved

ABSTRACT
 
Copper(II) biscomplexes of 3-bromo-6-chloro-8-quinolinol and 6-bromo-3-chloro-8-quinolinol were prepared, the long axes of which were 16.8 Å and 17.6 Å respectively. The long axes of the pores in the walls of the test fungi were determined: A niger (15.0 Å), A. oryzae (16.8 Å), M. verrucaria (17.4 Å), T. viride (15.0 Å). M. circinelloides (not determined), and T. menta-grophytes (17.4 Å). When the long axis of the copper(II) complex was was shorter or equal to that of the pore, there was fungitoxicity. When the long axis of the complex was longer than that of the pore in the fungal wall there was no toxicity. This was due to penetration or exclusion from the cell.
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