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Current Topics in Catalysis   Volumes    Volume 5 
Abstract
Strategies of design of Ni/MgO catalysts for the reforming of hydrocarbons to hydrogen/syngas
Francesco Arena, Adolfo Parmaliana
Pages: 69 - 88
Number of pages: 20
Current Topics in Catalysis
Volume 5 

Copyright © 2006 Research Trends. All rights reserved

ABSTRACT

Basic factors affecting the structure and the morphological properties of the Magnesia-Supported Nickel system are reviewed and the general strategy of catalyst design for the reforming of hydrocarbons to hydrogen/syngas is outlined. After the light of an“entropic” tendency of MgO and NiO to “mix”, forming true substitutional NixMg(1-x)O solid solutions, the crucial effects of synthesis route, metal loading and thermal treatments on the morphology and catalytic behaviour of the Ni/MgO system are assessed. The singular effects of “doping” on the morphology, electronic and catalytic properties are also documented.

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