This paper presents an overview on the coordination chemistry of Re with poly(pyrazolyl)borates of the type [R₂B(pz*)₂] (R=H, Ph, pyrazolyl; pz*=pyrazolyl or 3,5-dimethylpyrazolyl). This includes a variety of compounds like trioxo, dioxo, oxo, and hydrides with the metal in different oxidation states. Synthetic, spectroscopic, structural and other relevant aspects are reviewed.