2-(9-carbazolyl)ethyl methacrylate (CEM) and 7-diethyl-aminocoumarin-3-carboxylic acid 2-(methacryloyloxy)ethyl ester (MK) were synthesized and then copolymerized to give (99.5:0.5), (99:1), (98:2), and (92:8 mol/mol) CEM/MK copolymers. Starting materials for monomers synthesis: N-(2- hydroxyethyl) carbazole and 7-diethyloaminocoumarin-3-carboxylic acid were synthesized under microwave irradiation using novel modified methods. Solutions of the copolymers in THF were examined for their photoluminescence properties, while thin films made of the copolymers for electroluminescence properties.