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Trends in Heterocyclic Chemistry   Volumes    Volume 9 
Abstract
Synthesis of sugar analogs having a phosphorus atom in the pyranose ring (phospha sugar) and stereoselectivity of C-P bond introduction
Hiroshi Yamamoto, Tadashi Hanaya
Pages: 1 - 18
Number of pages: 18
Trends in Heterocyclic Chemistry
Volume 9 

Copyright © 2003 Research Trends. All rights reserved

ABSTRACT

Synthetic studies are reviewed on phospha sugars, sugar analogs having a phosphorus atom in the hemiacetal ring, e.g., analogs of D-glucose, D-mannose, D-galactose, L-fucose, D-fructose. By converting them into the corresponding per-o-acetyl derivatives, structures and conformations of phospha sugars have been established by 1H-NMR spectral analyses. Various methods and their stereoselectivity of the C-P bond introduction onto various types of 6-nitro-hex-5-enofuranoses, 6-o-tosyl-hexofuranos-5-uloses, and 6-o-benzyl-hexofuranos-5-uloses are also described.

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